Journal Description
Nanomaterials
Nanomaterials
is an international, peer-reviewed, interdisciplinary scholarly open access journal, published semimonthly online by MDPI. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. The Spanish Carbon Group (GEC) is affiliated with Nanomaterials and their members receive discounts on the article processing charges.
- Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
- High Visibility: indexed within Scopus, SCIE (Web of Science), PubMed, PMC, CAPlus / SciFinder, Inspec, and other databases.
- Journal Rank: JCR - Q1 (Physics, Applied) / CiteScore - Q1 (General Chemical Engineering)
- Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 13.6 days after submission; acceptance to publication is undertaken in 2.5 days (median values for papers published in this journal in the second half of 2023).
- Recognition of Reviewers: reviewers who provide timely, thorough peer-review reports receive vouchers entitling them to a discount on the APC of their next publication in any MDPI journal, in appreciation of the work done.
- Companion journals for Nanomaterials include: Nanomanufacturing and Applied Nano.
Impact Factor:
5.3 (2022);
5-Year Impact Factor:
5.4 (2022)
Latest Articles
Construction of Monolayer Ti3C2Tx MXene on Nickel Foam under High Electrostatic Fields for High-Performance Supercapacitors
Nanomaterials 2024, 14(10), 887; https://doi.org/10.3390/nano14100887 (registering DOI) - 19 May 2024
Abstract
Ti3C2Tx MXene, as a common two-dimensional material, has a wide range of applications in electrochemical energy storage. However, the surface forces of few-layer or monolayer Ti3C2Tx MXene lead to easy agglomeration, which hinders
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Ti3C2Tx MXene, as a common two-dimensional material, has a wide range of applications in electrochemical energy storage. However, the surface forces of few-layer or monolayer Ti3C2Tx MXene lead to easy agglomeration, which hinders the demonstration of its performance due to the characteristics of layered materials. Herein, we report a facile method for preparing monolayer Ti3C2Tx MXene on nickel foam to achieve a self-supporting structure for supercapacitor electrodes under high electrostatic fields. Moreover, the specific capacitance varies with the deposition of different-concentration monolayer Ti3C2Tx MXene on nickel foam. As a result, Ti3C2Tx/NF has a high specific capacitance of 319 mF cm−2 at 2 mA cm−2 and an excellent long-term cycling stability of 94.4% after 7000 cycles. It was observed that the areal specific capacitance increases, whereas the mass specific capacitance decreases with the increasing loading mass. Attributable to the effect of the high electrostatic field, the self-supporting structure of the Ti3C2Tx/NF becomes denser as the concentration of the monolayer Ti3C2Tx MXene ink increases, ultimately affecting its electrochemical performance. This work provides a simple way to overcome the agglomeration problem of few-layer or monolayer MXene, then form a self-supporting electrode exhibiting excellent electrochemical performance.
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(This article belongs to the Special Issue Nanomaterials for Supercapacitors)
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Recent Advances in the Photonic Curing of the Hole Transport Layer, the Electron Transport Layer, and the Perovskite Layers to Improve the Performance of Perovskite Solar Cells
by
Moulay Ahmed Slimani, Sylvain G. Cloutier and Ricardo Izquierdo
Nanomaterials 2024, 14(10), 886; https://doi.org/10.3390/nano14100886 (registering DOI) - 19 May 2024
Abstract
Perovskite solar cells (PSCs) have attracted increasing research interest, but their performance depends on both the choice of materials and the process used. The materials can typically be treated in solution, which makes them well suited for roll-to-roll processing methods, but their deposition
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Perovskite solar cells (PSCs) have attracted increasing research interest, but their performance depends on both the choice of materials and the process used. The materials can typically be treated in solution, which makes them well suited for roll-to-roll processing methods, but their deposition under ambient conditions requires overcoming some challenges to improve stability and efficiency. In this review, we highlight the latest advancements in photonic curing (PC) for perovskite materials, as well as for hole transport layer (HTL) and electron transport layer (ETL) materials. We present how PC parameters can be used to control the optical, electrical, morphological, and structural properties of perovskite HTL and ETL layers. Emphasizing the significance of these advancements for perovskite solar cells could further highlight the importance of this research and underline its essential role in creating more efficient and sustainable solar technology.
Full article
(This article belongs to the Special Issue Nanoelectronics: Materials, Devices and Applications)
Open AccessArticle
Tailored Triggering of High-Quality Multi-Dimensional Coupled Topological States in Valley Photonic Crystals
by
Guangxu Su, Jiangle He, Xiaofei Ye, Hengming Yao, Yaxuan Li, Junzheng Hu, Minghui Lu, Peng Zhan and Fanxin Liu
Nanomaterials 2024, 14(10), 885; https://doi.org/10.3390/nano14100885 (registering DOI) - 19 May 2024
Abstract
The combination of higher-order topological insulators and valley photonic crystals has recently aroused extensive attentions due to the great potential in flexible and efficient optical field manipulations. Here, we computationally propose a photonic device for the 1550 nm communication band, in which the
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The combination of higher-order topological insulators and valley photonic crystals has recently aroused extensive attentions due to the great potential in flexible and efficient optical field manipulations. Here, we computationally propose a photonic device for the 1550 nm communication band, in which the topologically protected electromagnetic modes with high quality can be selectively triggered and modulated on demand. Through introducing two valley photonic crystal units without any structural alteration, we successfully achieve multi-dimensional coupled topological states thanks to the diverse electromagnetic characteristics of two valley edge states. According to the simulations, the constructed topological photonic devices can realize Fano lines on the spectrum and show high-quality localized modes by tuning the coupling strength between the zero-dimensional valley corner states and the one-dimensional valley edge states. Furthermore, we extend the valley-locked properties of edge states to higher-order valley topological insulators, where the selected corner states can be directionally excited by chiral source. More interestingly, we find that the modulation of multi-dimensional coupled photonic topological states with pseudospin dependence become more efficient compared with those uncoupled modes. This work presents a valuable approach for multi-dimensional optical field manipulation, which may support potential applications in on-chip integrated nanophotonic devices.
Full article
(This article belongs to the Special Issue Photofunctional Nanomaterials and Nanostructures)
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Open AccessArticle
Direct Selective Epitaxy of 2D Sb2Te3 onto Monolayer WS2 for Vertical p–n Heterojunction Photodetectors
by
Baojun Pan, Zhenjun Dou, Mingming Su, Ya Li, Jialing Wu, Wanwan Chang, Peijian Wang, Lijie Zhang, Lei Zhao, Mei Zhao and Sui-Dong Wang
Nanomaterials 2024, 14(10), 884; https://doi.org/10.3390/nano14100884 (registering DOI) - 19 May 2024
Abstract
Two-dimensional transition metal dichalcogenides (2D-TMDs) possess appropriate bandgaps and interact via van der Waals (vdW) forces between layers, effectively overcoming lattice compatibility challenges inherent in traditional heterojunctions. This property facilitates the creation of heterojunctions with customizable bandgap alignments. However, the prevailing method for
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Two-dimensional transition metal dichalcogenides (2D-TMDs) possess appropriate bandgaps and interact via van der Waals (vdW) forces between layers, effectively overcoming lattice compatibility challenges inherent in traditional heterojunctions. This property facilitates the creation of heterojunctions with customizable bandgap alignments. However, the prevailing method for creating heterojunctions with 2D-TMDs relies on the low-efficiency technique of mechanical exfoliation. Sb2Te3, recognized as a notable p-type semiconductor, emerges as a versatile component for constructing diverse vertical p–n heterostructures with 2D-TMDs. This study presents the successful large-scale deposition of 2D Sb2Te3 onto inert mica substrates, providing valuable insights into the integration of Sb2Te3 with 2D-TMDs to form heterostructures. Building upon this initial advancement, a precise epitaxial growth method for Sb2Te3 on pre-existing WS2 surfaces on SiO2/Si substrates is achieved through a two-step chemical vapor deposition process, resulting in the formation of Sb2Te3/WS2 heterojunctions. Finally, the development of 2D Sb2Te3/WS2 optoelectronic devices is accomplished, showing rapid response times, with a rise/decay time of 305 μs/503 μs, respectively.
Full article
(This article belongs to the Special Issue 2D Materials and van der Waals Heterostructures for Optoelectronic Devices)
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Open AccessArticle
A Terahertz Metasurface Sensor Based on Quasi-BIC for Detection of Additives in Infant Formula
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Mingjun Sun, Jie Lin, Ying Xue, Weijin Wang, Shengnan Shi, Shan Zhang and Yanpeng Shi
Nanomaterials 2024, 14(10), 883; https://doi.org/10.3390/nano14100883 (registering DOI) - 19 May 2024
Abstract
Prohibited additives in infant formula severely affect the health of infants. Terahertz (THz) spectroscopy has enormous application potential in analyte detection due to its rich fingerprint information content. However, there is limited research on the mixtures of multiple analytes. In this study, we
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Prohibited additives in infant formula severely affect the health of infants. Terahertz (THz) spectroscopy has enormous application potential in analyte detection due to its rich fingerprint information content. However, there is limited research on the mixtures of multiple analytes. In this study, we propose a split ring metasurface that supports magnetic dipole bound states in the continuum (BIC). By breaking the symmetry, quasi-BIC with a high quality (Q) factor can be generated. Utilizing an angle-scanning strategy, the frequency of the resonance dip can be shifted, resulting in the plotting of an envelope curve which can reflect the molecular fingerprint of the analytes. Two prohibited additives found in infant formula, melamine and vanillin, can be identified in different proportions. Furthermore, a metric similar to the resolution in chromatographic analysis is introduced and calculated to be 0.61, indicating that these two additives can be detected simultaneously. Our research provides a new solution for detecting additives in infant formula.
Full article
(This article belongs to the Special Issue Nanomaterials for Terahertz Technology Applications)
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Open AccessArticle
Glass Ceramic Fibers Containing PbS Quantum Dots for Fluorescent Temperature Sensing
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Tingyu Zha, Penghui Zhang, Xilong Jin, Yi Long, Taoyun Huang, Hong Jia, Zaijin Fang and Bai-Ou Guan
Nanomaterials 2024, 14(10), 882; https://doi.org/10.3390/nano14100882 (registering DOI) - 19 May 2024
Abstract
Glass ceramics (GCs) containing PbS quantum dots (QDs) are prepared for temperature sensing. Broadband emissions are detected in the GCs when PbS QDs are precipitated from the glasses, and emissions centers are modulated from 1250 nm to 1960 nm via heat treatments. The
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Glass ceramics (GCs) containing PbS quantum dots (QDs) are prepared for temperature sensing. Broadband emissions are detected in the GCs when PbS QDs are precipitated from the glasses, and emissions centers are modulated from 1250 nm to 1960 nm via heat treatments. The emission centers of GCs exhibit blue-shifts when environment temperatures increase from room temperature to 210 °C. Importantly, the shift values of emission centers increase linearly with the test temperature, which is beneficial for applications in temperature sensing. A temperature sensor based on PbS QDs GC is heat-treated at 500 °C for 10 h, possesses the highest sensitivity of 0.378 nm/°C, and exhibits excellent stability and repeatability at high temperatures (up to 210 °C). Moreover, GC fibers are fabricated by using the GCs as the fiber core. The sensitivity of the temperature-sensing sensor of the GC fibers is also demonstrated and the sensitivity is as high as 0.558 nm/°C. The designed PbS QDs GCs provide a significant materials base for the manufacturing of fluorescent temperature sensors and the GC fibers offer significant opportunities for temperature detection in complex, integrated and compact devices.
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Open AccessArticle
Investigations of In2O3 Added SiC Semiconductive Thin Films and Manufacture of a Heterojunction Diode
by
Chia-Te Liao, Chia-Yang Kao, Zhi-Ting Su, Yu-Shan Lin, Yi-Wen Wang and Cheng-Fu Yang
Nanomaterials 2024, 14(10), 881; https://doi.org/10.3390/nano14100881 (registering DOI) - 19 May 2024
Abstract
This study involved direct doping of In2O3 into silicon carbide (SiC) powder, resulting in 8.0 at% In-doped SiC powder. Subsequently, heating at 500 °C was performed to form a target, followed by the utilization of electron beam (e-beam) technology to
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This study involved direct doping of In2O3 into silicon carbide (SiC) powder, resulting in 8.0 at% In-doped SiC powder. Subsequently, heating at 500 °C was performed to form a target, followed by the utilization of electron beam (e-beam) technology to deposit the In-doped SiC thin films with the thickness of approximately 189.8 nm. The first breakthrough of this research was the successful deposition of using e-beam technology. The second breakthrough involved utilizing various tools to analyze the physical and electrical properties of In-doped SiC thin films. Hall effect measurement was used to measure the resistivity, mobility, and carrier concentration and confirm its n-type semiconductor nature. The uniform dispersion of In ions in SiC was as confirmed by electron microscopy energy-dispersive spectroscopy and secondary ion mass spectrometry analyses. The Tauc Plot method was employed to determine the Eg values of pure SiC and In-doped SiC thin films. Semiconductor parameter analyzer was used to measure the conductivity and the I-V characteristics of devices in In-doped SiC thin films. Furthermore, the third finding demonstrated that In2O3-doped SiC thin films exhibited remarkable current density. X-ray photoelectron spectroscopy and Gaussian-resolved spectra further confirmed a significant relationship between conductivity and oxygen vacancy concentration. Lastly, depositing these In-doped SiC thin films onto p-type silicon substrates etched with buffered oxide etchant resulted in the formation of heterojunction p-n junction. This junction exhibited the rectifying characteristics of a diode, with sample current values in the vicinity of 102 mA, breakdown voltage at approximately −5.23 V, and open-circuit voltage around 1.56 V. This underscores the potential of In-doped SiC thin films for various semiconductor devices.
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(This article belongs to the Special Issue Advances in Wide-Bandgap Semiconductor Nanomaterials)
Open AccessArticle
Hectorite/Phenanthroline-Based Nanomaterial as Fluorescent Sensor for Zn Ion Detection: A Theoretical and Experimental Study
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Marina Massaro, Ana Borrego-Sánchez, César Viseras-Iborra, Giuseppe Cinà, Fátima García-Villén, Leonarda F. Liotta, Alberto Lopez Galindo, Carlos Pimentel, Claro Ignacio Sainz-Díaz, Rita Sánchez-Espejo and Serena Riela
Nanomaterials 2024, 14(10), 880; https://doi.org/10.3390/nano14100880 (registering DOI) - 19 May 2024
Abstract
The development of fluorescent materials that can act as sensors for the determination of metal ions in biological fluids is important since they show, among others, high sensitivity and specificity. However, most of the molecules that are used for these purposes possess a
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The development of fluorescent materials that can act as sensors for the determination of metal ions in biological fluids is important since they show, among others, high sensitivity and specificity. However, most of the molecules that are used for these purposes possess a very low solubility in aqueous media, and, thus, it is necessary to adopt some derivation strategies. Clay minerals, for example, hectorite, as natural materials, are biocompatible and available in large amounts at a very low cost that have been extensively used as carrier systems for the delivery of different hydrophobic species. In the present work, we report the synthesis and characterization of a hectorite/phenanthroline nanomaterial as a potential fluorescent sensor for Zn ion detection in water. The interaction of phenanthroline with the Ht interlaminar space was thoroughly investigated, via both theoretical and experimental studies (i.e., thermogravimetry, FT-IR, UV-vis and fluorescence spectroscopies and XRD measurements), while its morphology was imaged by scanning electron microscopy. Afterwards, the possibility to use it as sensor for the detection of Zn2+ ions, in comparison to other metal ions, was investigated through fluorescent measurements, and the stability of the solid Ht/Phe/Zn complex was assessed by different experimental and theoretical measurements.
Full article
(This article belongs to the Section Environmental Nanoscience and Nanotechnology)
Open AccessArticle
Controlling Thermoelectric Properties of Laser-Induced Graphene on Polyimide
by
Cem Kincal and Nuri Solak
Nanomaterials 2024, 14(10), 879; https://doi.org/10.3390/nano14100879 (registering DOI) - 19 May 2024
Abstract
In the field of wearable thermoelectric generators, graphene-based materials have attracted attention as suitable candidates due to their low material costs and tunable electronic properties. However, their high thermal conductivity poses significant challenges. Low thermal conductivity due to porous structure of the laser-induced
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In the field of wearable thermoelectric generators, graphene-based materials have attracted attention as suitable candidates due to their low material costs and tunable electronic properties. However, their high thermal conductivity poses significant challenges. Low thermal conductivity due to porous structure of the laser-induced graphene, combined with its affordability and scalability, positions it as a promising candidate for thermoelectric applications. In this study, thermoelectric properties of the laser-induced graphene (LIG) on polyimide and their dependence on structural modifications of LIG were investigated. Furthermore, it was shown that increasing the laser scribing power on polyimide results in larger graphene flakes and a higher degree of graphitization. Electrical conductivity measurements indicated an increase with increasing laser power, due to a higher degree of graphitization, which enhances charge carrier mobility. Our findings reveal that LIG exhibits p-type semiconducting behavior, characterized by a positive Seebeck coefficient. It was shown that increasing laser power increased the Seebeck coefficient and electrical conductivity simultaneously, which is attributed to a charge carrier energy filtering effect arising from structures occurred on the graphene flakes. Moreover, the porous structure of LIG contributes to its relatively low thermal conductivity, ranging between 0.6 W/m·K and 0.85 W/m·K, which enhances the thermoelectric performance of LIG. It has been observed that with increasing laser power, the figure of merit for laser-induced graphene can be enhanced by nearly 10 times, which holds promising applications for laser-induced graphene due to the tunability of its thermoelectric performance by changing laser parameters.
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(This article belongs to the Special Issue 2D and Carbon Nanomaterials for Energy Conversion and Storage)
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Novel Highly Efficient Buried Gratings for Selective Coupling of SPP Waves onto Single Interfaces
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Arif Nabizada, Hamed Tari, Alessandro Bile and Eugenio Fazio
Nanomaterials 2024, 14(10), 878; https://doi.org/10.3390/nano14100878 (registering DOI) - 18 May 2024
Abstract
Diffraction gratings have always been used to effectively couple optical radiation within integrated waveguides. This is also valid for plasmonic structures that support Surface Plasmon Polariton (SPP) waves. Traditional gratings usually excite SPP waves at the interface where they are located or, for
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Diffraction gratings have always been used to effectively couple optical radiation within integrated waveguides. This is also valid for plasmonic structures that support Surface Plasmon Polariton (SPP) waves. Traditional gratings usually excite SPP waves at the interface where they are located or, for thin metal nanostrips, at both interfaces. But reducing the thickness of the metal layer in the presence of a grating has the handicap of increasing the tunnelling of light towards the substrate, which means higher losses and reduced coupling efficiency. In this paper, we design and optimize novel gratings buried within the metallic thin films for selective coupling of SPP waves onto individual interfaces. Compared with traditional superficial gratings, the novel buried ones demonstrate higher efficiency and much lower residual tunnelling of light through the coupling structures.
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(This article belongs to the Section Theory and Simulation of Nanostructures)
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Bioaccessibility of Metallic Nickel and Nickel Oxide Nanoparticles in Four Simulated Biological Fluids
by
Tara Lyons-Darden, Katherine E. Heim, Li Han, Laura Haines, Christie M. Sayes and Adriana R. Oller
Nanomaterials 2024, 14(10), 877; https://doi.org/10.3390/nano14100877 (registering DOI) - 17 May 2024
Abstract
Bioaccessibility of metals from substances and alloys is increasingly used as part of the assessment to predict potential toxicity. However, data are sparse on the metal bioaccessibility from nanoparticle (NP) size metal substances. This study examines nickel ion release from metallic nickel and
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Bioaccessibility of metals from substances and alloys is increasingly used as part of the assessment to predict potential toxicity. However, data are sparse on the metal bioaccessibility from nanoparticle (NP) size metal substances. This study examines nickel ion release from metallic nickel and nickel oxide micron particles (MPs) and NPs in simulated biological fluids at various timepoints including those relevant for specific routes of exposure. The results suggest that MPs of both metallic nickel and nickel oxide generally released more nickel ions in acidic simulated biological fluids (gastric and lysosomal) than NPs of the same substance, with the largest differences being for nickel oxide. In more neutral pH fluids (interstitial and perspiration), nickel metal NPs released more nickel ions than MPs, with nickel oxide results showing a higher release for MPs in interstitial fluid yet a lower release in perspiration fluid. Various experimental factors related to the particle, fluid, and extraction duration were identified that can have an impact on the particle dissolution and release of nickel ions. Overall, the results suggest that based on nickel release alone, nickel NPs are not inherently more hazardous than nickel MPs. Moreover, analyses should be performed on a case-by-case basis with consideration of various experimental factors and correlation with in vivo data.
Full article
(This article belongs to the Section Biology and Medicines)
Open AccessArticle
Solvothermal Fabrication of Mesoporous Pd Nano-Corals at Mild Temperature for Alkaline Hydrogen Evolution Reaction
by
Ming Zhao, Koh-ichi Maruyama and Satoshi Tanaka
Nanomaterials 2024, 14(10), 876; https://doi.org/10.3390/nano14100876 (registering DOI) - 17 May 2024
Abstract
Porous metallic nanomaterials exhibit interesting physical and chemical properties, and are widely used in various fields. Traditional fabrication techniques are limited to metallurgy, sintering, electrodeposition, etc., which limit the control of pore size and distribution, and make it difficult to achieve materials with
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Porous metallic nanomaterials exhibit interesting physical and chemical properties, and are widely used in various fields. Traditional fabrication techniques are limited to metallurgy, sintering, electrodeposition, etc., which limit the control of pore size and distribution, and make it difficult to achieve materials with high surface areas. On the other hand, the chemical preparation of metallic nanoparticles is usually carried out with strong reducing agents or at high temperature, resulting in the formation of dispersed particles which cannot evolve into porous metal. In this study, we reported the simple fabrication of coral-like mesoporous Pd nanomaterial (Pd NC) with a ligament size of 4.1 nm. The fabrication was carried out by simple solvothermal reduction at a mild temperature of 135 °C, without using any templates. The control experiments suggested that tetrabutylammonium bromide (TBAB) played a critical role in the Pd(II) reduction into Pd nanoclusters and their subsequent aggregation to form Pd NC, and another key point for the formation of Pd NC is not to use a strong reducing agent. In alkaline water electrolysis, the Pd NC outperforms the monodisperse Pd NPs and the state-of-the-art Pt (under large potentials) for H2 evolution reaction, probably due to its mesoporous structure and large surface area. This work reports a simple and novel method for producing porous metallic nanomaterials with a high utilization efficiency of metal atoms, and it is expected to contribute to the practical preparation of porous metallic nanomaterials by solvothermal reductions.
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(This article belongs to the Special Issue Metallic Nanomaterial Applications in Selective Catalysis and Clean Energy)
Open AccessArticle
Raman Scattering Enhancement through Pseudo-Cavity Modes
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Vincenzo Caligiuri, Antonello Nucera, Aniket Patra, Marco Castriota and Antonio De Luca
Nanomaterials 2024, 14(10), 875; https://doi.org/10.3390/nano14100875 - 17 May 2024
Abstract
Raman spectroscopy plays a pivotal role in spectroscopic investigations. The small Raman scattering cross-section of numerous analytes, however, requires enhancement of the signal through specific structuring of the electromagnetic and morphological properties of the underlying surface. This enhancement technique is known as surface-enhanced
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Raman spectroscopy plays a pivotal role in spectroscopic investigations. The small Raman scattering cross-section of numerous analytes, however, requires enhancement of the signal through specific structuring of the electromagnetic and morphological properties of the underlying surface. This enhancement technique is known as surface-enhanced Raman spectroscopy (SERS). Despite the existence of various proposed alternatives, the approach involving Fabry–Pérot cavities, which constitutes a straightforward method to enhance the electromagnetic field around the analyte, has not been extensively utilized. This is because, for the analyte to experience the maximum electric field, it needs to be embedded within the cavity. Consequently, the top mirror of the cavity will eventually shield it from the external laser source. Recently, an open-cavity configuration has been demonstrated to exhibit properties similar to the classic Fabry–Pérot configuration, with the added advantage of maintaining direct accessibility for the laser source. This paper showcases how such a simple yet innovative configuration can be effectively utilized to achieve remarkable Raman enhancement. The simple structure, coupled with its inexpensive nature and versatility in material selection and scalability, makes it an ideal choice for various analytes and integration into diverse Raman apparatus setups.
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(This article belongs to the Special Issue Recent Research on Nanophotonics and Nanoscale Quantum Optics)
Open AccessArticle
Magnetic-Dielectric Cantilevers for Atomic Force Microscopy
by
Gala Sanchez-Seguame, Hugo Avalos-Sanchez, Jesus Eduardo Lugo, Eduardo Antonio Murillo-Bracamontes, Martha Alicia Palomino-Ovando, Orlando Hernández-Cristobal, José Juan Gervacio-Arciniega and Miller Toledo-Solano
Nanomaterials 2024, 14(10), 874; https://doi.org/10.3390/nano14100874 - 17 May 2024
Abstract
Atomic force microscopy (AFM) is a technique that relies on detecting forces at the nanonewton scale. It involves using a cantilever with a tiny tip at one end. This tip interacts with the short- and long-range forces of material surfaces. These cantilevers are
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Atomic force microscopy (AFM) is a technique that relies on detecting forces at the nanonewton scale. It involves using a cantilever with a tiny tip at one end. This tip interacts with the short- and long-range forces of material surfaces. These cantilevers are typically manufactured with Si or Si3N4 and synthesized using a lithography technique, which implies a high cost. On the other hand, through simple chemical methods, it is possible to synthesize a magneto-dielectric composite made up of artificial SiO2 opals infiltrated with superparamagnetic nanoparticles of Fe3O4. From these materials, it is possible to obtain tipless cantilevers that can be used in AFM analysis. Tipless cantilevers are an alternative tool in nanoscale exploration, offering a versatile approach to surface analysis. Unlike traditional AFM probes, tipless versions eliminate the challenges associated with tip wear, ensuring prolonged stability during measurements. This makes tipless AFM particularly valuable for imaging delicate or soft samples, as it prevents sample damage and provides precise measurements of topography and mechanical and electromechanical properties. This study presents the results of the characterization of known surfaces using magneto-dielectric cantilevers and commercial cantilevers based on Si. The characterization will be carried out through contact and non-contact topography measurements.
Full article
(This article belongs to the Special Issue Characterization and Applications of Nanomaterials in Sensors and Actuators)
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Open AccessArticle
Edge-Terminated AlGaN/GaN/AlGaN Multi-Quantum Well Impact Avalanche Transit Time Sources for Terahertz Wave Generation
by
Monisha Ghosh, Shilpi Bhattacharya Deb, Aritra Acharyya, Arindam Biswas, Hiroshi Inokawa, Hiroaki Satoh, Amit Banerjee, Alexy Y. Seteikin and Ilia G. Samusev
Nanomaterials 2024, 14(10), 873; https://doi.org/10.3390/nano14100873 - 17 May 2024
Abstract
In our pursuit of high-power terahertz (THz) wave generation, we propose innovative edge-terminated single-drift region (SDR) multi-quantum well (MQW) impact avalanche transit time (IMPATT) structures based on the AlxGa1−xN/GaN/AlxGa1−xN material system, with a
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In our pursuit of high-power terahertz (THz) wave generation, we propose innovative edge-terminated single-drift region (SDR) multi-quantum well (MQW) impact avalanche transit time (IMPATT) structures based on the AlxGa1−xN/GaN/AlxGa1−xN material system, with a fixed aluminum mole fraction of x = 0.3. Two distinct MQW diode configurations, namely p+-n junction-based and Schottky barrier diode structures, were investigated for their THz potential. To enhance reverse breakdown characteristics, we propose employing mesa etching and nitrogen ion implantation for edge termination, mitigating issues related to premature and soft breakdown. The THz performance is comprehensively evaluated through steady-state and high-frequency characterizations using a self-consistent quantum drift-diffusion (SCQDD) model. Our proposed Al0.3Ga0.7N/GaN/Al0.3Ga0.7N MQW diodes, as well as GaN-based single-drift region (SDR) and 3C-SiC/Si/3C-SiC MQW-based double-drift region (DDR) IMPATT diodes, are simulated. The Schottky barrier in the proposed diodes significantly reduces device series resistance, enhancing peak continuous wave power output to approximately 300 mW and DC to THz conversion efficiency to nearly 13% at 1.0 THz. Noise performance analysis reveals that MQW structures within the avalanche zone mitigate noise and improve overall performance. Benchmarking against state-of-the-art THz sources establishes the superiority of our proposed THz sources, highlighting their potential for advancing THz technology and its applications.
Full article
(This article belongs to the Special Issue Nanomaterials for Terahertz Technology Applications)
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Direct Imaging of Radiation-Sensitive Organic Polymer-Based Nanocrystals at Sub-Ångström Resolution
by
Elvio Carlino, Antonietta Taurino, Dritan Hasa, Dejan-Krešimir Bučar, Maurizio Polentarutti, Lidia E. Chinchilla and Josè J. Calvino Gamez
Nanomaterials 2024, 14(10), 872; https://doi.org/10.3390/nano14100872 - 17 May 2024
Abstract
Seeing the atomic configuration of single organic nanoparticles at a sub-Å spatial resolution by transmission electron microscopy has been so far prevented by the high sensitivity of soft matter to radiation damage. This difficulty is related to the need to irradiate the particle
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Seeing the atomic configuration of single organic nanoparticles at a sub-Å spatial resolution by transmission electron microscopy has been so far prevented by the high sensitivity of soft matter to radiation damage. This difficulty is related to the need to irradiate the particle with a total dose of a few electrons/Å2, not compatible with the electron beam density necessary to search the low-contrast nanoparticle, to control its drift, finely adjust the electron-optical conditions and particle orientation, and finally acquire an effective atomic-resolution image. On the other hand, the capability to study individual pristine nanoparticles, such as proteins, active pharmaceutical ingredients, and polymers, with peculiar sensitivity to the variation in the local structure, defects, and strain, would provide advancements in many fields, including materials science, medicine, biology, and pharmacology. Here, we report the direct sub-ångström-resolution imaging at room temperature of pristine unstained crystalline polymer-based nanoparticles. This result is obtained by combining low-dose in-line electron holography and phase-contrast imaging on state-of-the-art equipment, providing an effective tool for the quantitative sub-ångström imaging of soft matter.
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(This article belongs to the Special Issue Transmission Electron Microscopy for Nanomaterials Research Advances)
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Upconversion Emission and Dual-Mode Sensing Characteristics of NaYF4:Yb3+/Er3+ Microcrystals at High and Ultralow Temperatures
by
Xinyi Xu, Zhaojin Wang, Jin Hou, Tian Zhang, Xin Zhao, Siyi Di and Zijie Li
Nanomaterials 2024, 14(10), 871; https://doi.org/10.3390/nano14100871 - 17 May 2024
Abstract
In this study, we investigate micrometer-sized NaYF4 crystals double-doped with Yb3+/Er3+ lanthanide ions, designed for temperature-sensing applications. In contrast to previous studies, which focused predominantly on the high-temperature regime, our investigation spans a comprehensive range of both high and
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In this study, we investigate micrometer-sized NaYF4 crystals double-doped with Yb3+/Er3+ lanthanide ions, designed for temperature-sensing applications. In contrast to previous studies, which focused predominantly on the high-temperature regime, our investigation spans a comprehensive range of both high and ultralow temperatures. We explore the relationship between temperature and the upconversion luminescence (UCL) spectra in both frequency and time domains. Our findings highlight the strong dependence of these spectral characteristics of lanthanide-doped NaYF4 crystals on temperature. Furthermore, we introduce a dual-mode luminescence temperature measurement technique, leveraging the upconversion emission intensity ratio for both green and red emissions. This study also examines the correlation between temperature sensing, energy level disparities, and thermal coupling in Er3+ ions across various temperature scales. Our research contributes to advancing the understanding and application of lanthanide-doped materials, setting a foundation for future innovations in temperature sensing across diverse fields.
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(This article belongs to the Special Issue Luminescent Nanomaterials: Functional Design, Advantages, and Applications)
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Open AccessArticle
Effect of Post-Implantation Heat Treatment Conditions on Photoluminescent Properties of Ion-Synthesized Gallium Oxide Nanocrystals
by
Dmitry S. Korolev, Kristina S. Matyunina, Alena A. Nikolskaya, Alexey I. Belov, Alexey N. Mikhaylov, Artem A. Sushkov, Dmitry A. Pavlov and David I. Tetelbaum
Nanomaterials 2024, 14(10), 870; https://doi.org/10.3390/nano14100870 - 17 May 2024
Abstract
A novel and promising way for creating nanomaterials based on gallium oxide is the ion synthesis of Ga2O3 nanocrystals in a SiO2/Si dielectric matrix. The properties of nanocrystals are determined by the conditions of ion synthesis—the parameters of
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A novel and promising way for creating nanomaterials based on gallium oxide is the ion synthesis of Ga2O3 nanocrystals in a SiO2/Si dielectric matrix. The properties of nanocrystals are determined by the conditions of ion synthesis—the parameters of ion irradiation and post-implantation heat treatment. In this work, the light-emitting properties of Ga2O3 nanocrystals were studied depending on the temperature and annealing atmosphere. It was found that annealing at a temperature of 900 °C leads to the appearance of intense luminescence with a maximum at ~480 nm caused by the recombination of donor–acceptor pairs. An increase in luminescence intensity upon annealing in an oxidizing atmosphere is shown. Based on data from photoluminescence excitation spectroscopy and high-resolution transmission electron microscopy, a hypothesis about the possibility of the participation of a quantum-size effect during radiative recombination is proposed. A mechanism for the formation of Ga2O3 nanocrystals during ion synthesis is suggested, which makes it possible to describe the change in the luminescent properties of the synthesized samples with varying conditions of post-implantation heat treatment.
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(This article belongs to the Special Issue Advances in Wide-Bandgap Semiconductor Nanomaterials)
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Open AccessArticle
Enhanced Thermal Stability of Carbonyl Iron Nanocrystalline Microwave Absorbents by Pinning Grain Boundaries with SiBaFe Alloy Nanoparticles
by
Yifan Xu, Zhihong Chen, Ziwen Fu, Yuchen Hu, Yunhao Luo, Wei Li and Jianguo Guan
Nanomaterials 2024, 14(10), 869; https://doi.org/10.3390/nano14100869 - 16 May 2024
Abstract
Nanocrystalline carbonyl iron (CI) particles are promising microwave absorbents at elevated temperature, whereas their excessive grain boundary energy leads to the growth of nanograins and a deterioration in permeability. In this work, we report a strategy to enhance the thermal stability of the
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Nanocrystalline carbonyl iron (CI) particles are promising microwave absorbents at elevated temperature, whereas their excessive grain boundary energy leads to the growth of nanograins and a deterioration in permeability. In this work, we report a strategy to enhance the thermal stability of the grains and microwave absorption of CI particles by doping a SiBaFe alloy. Grain growth was effectively inhibited by the pinning effect of SiBaFe alloy nanoparticles at the grain boundaries. After heat treatment at 600 °C, the grain size of CI particles increased from ~10 nm to 85.1 nm, while that of CI/SiBaFe particles was only 32.0 nm; with the temperature rising to 700 °C, the grain size of CI particles sharply increased to 158.1 nm, while that of CI/SiBaFe particles was only 40.8 nm. Excellent stability in saturation magnetization and microwave absorption was also achieved in CI/SiBaFe particles. After heat treatment at 600 °C, the flaky CI/SiBaFe particles exhibited reflection loss below −10 dB over 7.01~10.11 GHz and a minimum of −14.92 dB when the thickness of their paraffin-based composite was 1.5 mm. We provided a low-cost and efficient kinetic strategy to stabilize the grain size in nanoscale and microwave absorption for nanocrystalline magnetic absorbents working at elevated temperature.
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(This article belongs to the Special Issue Advances in Stimuli-Responsive Nanomaterials II)
Open AccessArticle
Growth of Quasi-Two-Dimensional CrTe Nanoflakes and CrTe/Transition Metal Dichalcogenide Heterostructures
by
Dawei Cheng, Jiayi Liu and Bin Wei
Nanomaterials 2024, 14(10), 868; https://doi.org/10.3390/nano14100868 - 16 May 2024
Abstract
Two-dimensional (2D) van der Waals layered materials have been explored in depth. They can be vertically stacked into a 2D heterostructure and represent a fundamental way to explore new physical properties and fabricate high-performance nanodevices. However, the controllable and scaled growth of non-layered
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Two-dimensional (2D) van der Waals layered materials have been explored in depth. They can be vertically stacked into a 2D heterostructure and represent a fundamental way to explore new physical properties and fabricate high-performance nanodevices. However, the controllable and scaled growth of non-layered quasi-2D materials and their heterostructures is still a great challenge. Here, we report a selective two-step growth method for high-quality single crystalline CrTe/WSe2 and CrTe/MoS2 heterostructures by adopting a universal CVD strategy with the assistance of molten salt and mass control. Quasi-2D metallic CrTe was grown on pre-deposited 2D transition metal dichalcogenides (TMDC) under relatively low temperatures. A 2D CrTe/TMDC heterostructure was established to explore the interface’s structure using scanning transmission electron microscopy (STEM), and also demonstrate ferromagnetism in a metal–semiconductor CrTe/TMDC heterostructure.
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(This article belongs to the Special Issue Nano-Structured Thin Films: Growth, Characteristics, and Application)
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